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Anomalous thermal relaxations of physical systems

13 sept. 2023, 10:00
1h
Institut Pascal

Institut Pascal

Bâtiment 530, Rue André Rivière 91400 Orsay

Orateur

Marija Vucelja (University of Virginia)

Description

Rapid cooling or heating of a physical system can lead to unusual thermal relaxation phenomena. A prime example of anomalous thermal relaxation is the Mpemba effect. The phenomenon occurs when a system prepared at a hot temperature overtakes an identical system prepared at a warm temperature and equilibrates faster to the cold environment. A similar effect exists in heating. Comparing two identical physical systems in their equilibration, we would expect that the system with a smaller mismatch between its and the environment's temperature will thermalize faster -- yet it is not always the case.

I will present theoretical results on the Mpemba effect in over-damped Langevin dynamics and Markov jump processes. I will link the Mpemba effect's occurrence with the physical systems' properties and dynamics. In particular, I will derive the necessary conditions for the Mpemba effect in the small diffusion limit of one-dimensional over-damped Langevin dynamics on a double-well potential. Next, I will provide analytical results and insights on when the Mpemba effect happens in Markov jump processes as a function of the dynamics. I will explore the connections between the Mpemba effect and optimal transport. I will also discuss potential applications of anomalous thermal relaxations in MCMC sampling.

This material is based upon work supported by the National Science Foundation under Grant No. DMR-1944539.

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