Orateur
Description
In the framework of ultra-cold chemistry, where reactions can be studied in well-defined quantum states, collisional phenomena between cations and neutral atoms are still not fully understood. Widely used semi-classical capture models, such as the one of Langevin [1], fail in some cases in predicting correctly rate constants associated to the charge transfer between two such species. The discrepancies between these models and experiment usually indicate that the detailed shape of the relevant potential energy surfaces (PES) at short ion-atom distance are determining in the reaction dynamics [2].
Ion-atom hybrid trap experiments capable of handling molecular ions and atoms at temperatures in the millikelvin regime allow for measuring charge transfer reaction rate constants with precision. We present here the results for the collision between the prototypical triatomic ion N
[1] G. Gioumousis and D. P. Stevenson, J. Chem. Phys. 29, 294-299 (1958)
[2] A. Dörfler, P. Eberle, D. Koner, M. Tomza, M. Meuwly and S. Willitsch, Nat. Comm. 10, 5429 (2019)
[3] A. Voute, A. Dörfler, L. Wiesenfeld, O. Dulieu, F. Gatti, D. Peláez and S. Willitsch, (2023), [under review]
Affiliation de l'auteur principal | Institut des Sciences Moléculaires d'Orsay, Laboratoire Aimé Cotton |
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